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31.
Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.  相似文献   
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The Arsenopyrite Residue Stockpile (ARS) in Snow Lake, Manitoba contains approximately 250,000 tons of cyanide treated, refractory arsenopyrite ore concentrate. The residue was deposited between 1950 and 1959 in an open waste rock impoundment, and remained exposed until 2000, when the pile was capped with layers of waste rock and clay. During the time when the ARS was exposed to the atmosphere, arsenopyrite, pyrrhotite, pyrite and chalcopyrite were oxidized producing scorodite, jarosite and two generations of amorphous Fe sulfo-arsenates (AISA). These secondary phases attenuated some of the As released to pore water during oxidation in the upper layers of the ARS. The imposition of the cap prevented further oxidation. The secondary As minerals are not stable in the reduced environment that currently dominates the pile. Therefore, As currently is being released into the groundwater. Water in an adjacent monitoring well has concentrations of >20 mg/L total As with relative predominance of As(III).  相似文献   
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In 2009, the Russian Complex Orbital Observations Near-Earth of Activity of the Sun (CORONAS-Photon) spacecraft was launched, carrying the Polish Solar PHotometer In X-rays (SphinX). The SphinX was most sensitive in the spectral range 1.2?–?15 keV, thus an excellent opportunity appeared for comparison with the low-energy end of Ramaty High Energy Solar Spectroscopic Imager (RHESSI) spectra. Common spectral measurements with these instruments cover the range where most of the flare energy is accumulated. We have chosen four consecutive small solar events observed on 4 July 2009 at 13:43 UT, 13:48 UT, 13:52 UT, and 13:55 UT (RHESSI flare peak times) and used them to compare the data and results from the two instruments. Moreover, we included Geostationary Operational Environmental Satellite (GOES) records in our analysis. In practice, the range of comparison performed for SphinX and RHESSI is limited roughly to 3?–?6 keV. RHESSI fluxes measured with a use of one, four, and nine detectors in the 3?–?4 keV energy band agree with SphinX measurements. However, we observed that SphinX spectral irradiances are three times higher than those of RHESSI in the 4?–?6 keV energy band. This effect contributes to the difference in obtained emission measures, but the derived temperatures of plasma components are similar. RHESSI spectra were fitted using a model with two thermal components. We have found that the RHESSI hot component is in agreement with GOES, and the RHESSI hotter component fits the SphinX flaring component well. Moreover, we calculated the so-called thermodynamic measure and the total thermal energy content in the four microflares that we studied. The results obtained show that SphinX is a very sensitive complementary observatory for RHESSI and GOES.  相似文献   
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Obsidian is abundant in the Main Ethiopian Rift (MER). Petrological and geochemical features of obsidian from four volcanic centers in the MER, namely Birenti, Dofen, Fentale and Kone, are presented. Compositional and petrological variability is noted among the Dofen and Fentale obsidian, but not in those from Kone and Birenti where each have separate but uniform elemental composition. The Fentale and Kone obsidian were source materials for the artifacts of a number of Middle Stone Age and Later Stone Age/Neolithic sites in the region. We have yet to determine whether Dofen and Birenti were sources for archeological artifacts. The study also shows that volcanic episodes from a single center do not necessarily result in compositional variability.  相似文献   
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The management of groundwater resources is very important in the semiarid Sahel region, which is experiencing rapid urban development. Impacts of urbanization on groundwater resources were investigated in the unconfined aquifer of the Continental Terminal beneath the city of Niamey, Niger, using water level and chemical data. Hydrodynamic and chemical changes are best described by a combination of factors including the historical development of the city, current land use, water-table depth and topography. Seasonal groundwater recharge occurs with high spatial variability, as indicated by water-level monitoring in all wells, but there was no interannual trend over the 5-year study period. Groundwater salinity shows high spatial variability and a minor rising trend. The highest salinity is in the old city centre, with Na–NO3 dominant, and it increases seasonally with recharge. Salinity is much lower and more variable in the suburbs (Ca–HCO3, Ca–NO3, and Na–NO3 dominant). Nitrate is the main ionic contaminant and is seasonally or permanently above the international guidelines for drinking water quality in 36 % of sampled wells, with a peak value of 112 mg L?1 NO3–N (8 meq L?1). Comparison of urban and rural sites indicates a long-term increase in groundwater recharge and nitrate enrichment in the urban area with serious implications for groundwater management in the region.  相似文献   
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Estuaries are productive and ecologically important ecosystems, incorporating environmental drivers from watersheds, rivers, and the coastal ocean. Climate change has potential to modify the physical properties of estuaries, with impacts on resident organisms. However, projections from general circulation models (GCMs) are generally too coarse to resolve important estuarine processes. Here, we statistically downscaled near-surface air temperature and precipitation projections to the scale of the Chesapeake Bay watershed and estuary. These variables were linked to Susquehanna River streamflow using a water balance model and finally to spatially resolved Chesapeake Bay surface temperature and salinity using statistical model trees. The low computational cost of this approach allowed rapid assessment of projected changes from four GCMs spanning a range of potential futures under a high CO2 emission scenario, for four different downscaling methods. Choice of GCM contributed strongly to the spread in projections, but choice of downscaling method was also influential in the warmest models. Models projected a ~2–5.5 °C increase in surface water temperatures in the Chesapeake Bay by the end of the century. Projections of salinity were more uncertain and spatially complex. Models showing increases in winter-spring streamflow generated freshening in the Upper Bay and tributaries, while models with decreased streamflow produced salinity increases. Changes to the Chesapeake Bay environment have implications for fish and invertebrate habitats, as well as migration, spawning phenology, recruitment, and occurrence of pathogens. Our results underline a potentially expanded role of statistical downscaling to complement dynamical approaches in assessing climate change impacts in dynamically challenging estuaries.  相似文献   
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